Though rumors that they were a serious item had reached a fever pitch, they continued to refuse to confirm anything.Following the paparazzi images of the couple together in Kenya, many considered the shoot a major affront to Aniston, as her divorce from Pitt had not yet been finalized. A month after Brad's ex, Jennifer Aniston, filed for divorce, pictures emerged of Angelina, Brad and her son Maddox at a beach in Kenya. Smith' and their relationship caused a nuclear meltdown of the tabloid machine.Due to scheduling conflicts, they hadn't met before filming their first scene.At this point, Pitt and Jennifer Aniston had been married for nearly five years, while Jolie was still considered a wild card with unusual taste.» Summer 2004: Pitt and Jolie meet on the set of "Mr. Smith." Rumors of an on-set romance begin almost immediately, though both deny the allegations, saying they are just friends.» January 2005: Pitt and then-wife Jennifer Aniston announce that they have decided to formally separate after nearly five years of marriage and more than seven years together.
Let's take a look back at all of Brangelina's most important moments., a steamy action-comedy movie about two (married) spies.
As well as seven-year-old Maddox and three-year-old Zahara, they are also parents to Vietnamese Pax, five; Shiloh Nouvel, two; and twins Knox and Vivienne, five months.
Last month, Aniston admitted to being unhappy with Jolie's conduct over some of the details of her relationship with Pitt.
After years of speculation, Brad Pitt has finally admitted he fell in love with Angelina Jolie while he was still married to Jennifer Aniston.
Rumours swirled around Pitt and Jolie while they were filming Mr & Mrs Smith in May 2004 - seven months before he split from the former Friends star.